Structural Aspects Of Diaquotetrakis (imidazole) Cobalt II Choloride
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Date
2012
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Abstract
A pink coloured cobalt(Il) complex viz., [Co(Imi)4(H20)2]Cl2 was prepared by mixing cobalt(II) chloride with imidazole in 1:4 molar
ratio in acetone. The complex was characterized by UV, IR, TG-DTA and single crystal XRD studies. The ERR spectrum of the complex
proved its paramagnetic nature which was further analyzed by magnetic susceptibility studies. Susceptibility measurements showed the
presence of three unpaired electrons accounting for the high spin nature o f the complex.